Skip to content

Category Archives: Chemistry

Element 112 officially “Copernicium”

07-Mar-10

decaychain112.png

Admittedly, if you’re not a chemist or physicist, you may find this post as boring as dirt. (Please forgive the simile, microbiologists. I know dirt is actually fascinating.) Then again, it’s not everyday a new element is added to the periodic table.

The latest addition, number 112, was discovered on February, 9th, 1996 at 10:37 PM by a team under Professor Sigurd Hofmann at the GSI Helmholtzzentrum für Schwerionenforschung (Center for Heavy Ion Research) in Darmstadt, Germany, who confirmed its existence by observing a characteristic “decay chain” of radioisotopes (illustrated above) that could only have originated with element 112.

Just a couple weeks ago, on February 19, that discovery was officially confirmed by the International Union of Pure and Applied Chemistry (IUPAC), who accepted the GSI team’s recommendation of the name “Copernicium” in honor, naturally, of Nicolaus Copernicus, whom most will recall as the first scientist to stand up and declare that the earth revolves around the sun, rather than the other way ’round. The new two-letter symbol is “Cn.”

Read more | Permalink | Comments |

Read more articles in Chemistry |

Digg this!

Share and Enjoy:
  • Digg
  • del.icio.us
  • Netvouz
  • DZone
  • ThisNext
  • MisterWong
  • Wists
  • Add to favorites
  • blogtercimlap
  • Facebook
  • Google Bookmarks
  • Gwar
  • LinkaGoGo
  • Live
  • MSN Reporter
  • MyShare
  • RSS
  • Slashdot
  • StumbleUpon
  • Suggest to Techmeme via Twitter
  • Technorati
  • Twitter

Maker Birthday: Linus Pauling

01-Mar-10

MZ_MakerBirthday.gif

pauling1.jpg

Yesterday, February 28, 2010, Linus Carl Pauling would’ve been 109 years old. And we’d all be better off he were still with us since, by all accounts, even a doddering Pauling could’ve run rings around most folks intellectually. One of four human beings ever to have been awarded multiple Nobel Prizes, and the only one ever to have won both the Nobel Prize for Chemistry (1954) and the Nobel Peace Prize (1962), Pauling’s 1939 Nature of the Chemical Bond remains one of the most influential chemistry texts ever published. And his 1947 General Chemistry, available in its classic 3rd edition through Dover Publications for a song, remains one of the best-written and most readable introductions to the subject. The Nobel Peace Prize was awarded for his instrumental role in scientific activism to end above-ground nuclear weapons testing. A complete list of Pauling’s accolades could, and has, filled several books, but I can’t resist mentioning, in closing, that geek ubermensch Linus Torvalds is reportedly named after him.

Read more | Permalink | Comments |

Read more articles in Chemistry |

Digg this!

Share and Enjoy:
  • Digg
  • del.icio.us
  • Netvouz
  • DZone
  • ThisNext
  • MisterWong
  • Wists
  • Add to favorites
  • blogtercimlap
  • Facebook
  • Google Bookmarks
  • Gwar
  • LinkaGoGo
  • Live
  • MSN Reporter
  • MyShare
  • RSS
  • Slashdot
  • StumbleUpon
  • Suggest to Techmeme via Twitter
  • Technorati
  • Twitter

Time lapse video of ‘tin pest’ metallic phase change

24-Feb-10

What’s going on in this cool time-lapse video from Italian YouTuber wwwperiodictableru isn’t a chemical reaction in a formal sense. It’s not oxidation or some other type of traditional corrosion. Turns out metallic or “white” tin spontaneously changes its so-called beta crystal structure at temperatures below 13 C to the crumbly alpha structure of “grey” tin. It’s the same stuff before and after–just different allotropes of the same element. The transformation, known as “tin pest” (Wikipedia), catalyzes itself–once it starts it just gets faster and faster.

There is a popular, if scientifically dubious, story that blames part of the failure of Napoleon’s infamous Russian campaign on the fact that the buttons on his soldiers’ coats were made of white tin, which was fine in Europe, but decayed into useless gray tin in the brutal cold of the Russian winter, and thereby prevented them from properly buttoning their coats. Implausible for lots of reasons, it turns out, but still a good yarn.

[Thanks, William Beaty!]

Read more | Permalink | Comments |

Read more articles in Chemistry |

Digg this!

Share and Enjoy:
  • Digg
  • del.icio.us
  • Netvouz
  • DZone
  • ThisNext
  • MisterWong
  • Wists
  • Add to favorites
  • blogtercimlap
  • Facebook
  • Google Bookmarks
  • Gwar
  • LinkaGoGo
  • Live
  • MSN Reporter
  • MyShare
  • RSS
  • Slashdot
  • StumbleUpon
  • Suggest to Techmeme via Twitter
  • Technorati
  • Twitter

Thermal lance is every bit as awesome as it sounds

23-Feb-10

This is a video, from YouTuber OliKills, showing two guys using a thermal lance (Wikipedia), also called a “thermic lance” or “burning bar,” to cut through a lump of concrete. It really gets going about 20 seconds in, and by the end of the video a white-hot stream of molten concrete “lava” is clearly visible running across the pavement.

If you’re a fan of Mythbusters, or you’ve seen…

Read more | Permalink | Comments |

Read more articles in Chemistry |

Digg this!

Share and Enjoy:
  • Digg
  • del.icio.us
  • Netvouz
  • DZone
  • ThisNext
  • MisterWong
  • Wists
  • Add to favorites
  • blogtercimlap
  • Facebook
  • Google Bookmarks
  • Gwar
  • LinkaGoGo
  • Live
  • MSN Reporter
  • MyShare
  • RSS
  • Slashdot
  • StumbleUpon
  • Suggest to Techmeme via Twitter
  • Technorati
  • Twitter

Microfluidics with common thread

21-Feb-10

am-2009-006148_0006.gif

“Microfluidics” (Wikipedia) is kind of a blanket term that covers manipulation of liquids on a very small scale. An inkjet printer head is an everyday example of a microfluidic system, but many of the more exciting applications are in biochemistry and/or medical diagnostics, where mass-produced “lab-on-a-chip” systems incorporating complex networks of tiny fluid channels could one day bring complex analytical procedures, that once were practical only in the laboratory, out into the field. Many of the same technologies that are used in the production of semiconductors can be applied to the manufacture of microfluidic systems.

As in semiconductors, however, the costs of prototyping labs-on-chips can be quite high. Many of you may recall the buzz surrounding UC-Irvine professor Michelle Khine’s recent discovery that inkjet-printable shrinky-dink plastic could be used to rapidly prototype microfluidic systems.

Read more | Permalink | Comments |

Read more articles in Chemistry |

Digg this!

Share and Enjoy:
  • Digg
  • del.icio.us
  • Netvouz
  • DZone
  • ThisNext
  • MisterWong
  • Wists
  • Add to favorites
  • blogtercimlap
  • Facebook
  • Google Bookmarks
  • Gwar
  • LinkaGoGo
  • Live
  • MSN Reporter
  • MyShare
  • RSS
  • Slashdot
  • StumbleUpon
  • Suggest to Techmeme via Twitter
  • Technorati
  • Twitter

How-To: Make the key glowstick chemical yourself

19-Feb-10

I have lots of hare-brained projects involving chemiluminescence that are currently back-burnered because the chemical that causes the bright chemiluminescence of commercial glowsticks, i.e. trichlorophenyl oxalate (TCPO, shown below), is relatively hard for hobbyists to acquire. I’ve even gone to the trouble of setting up a business account with a major chemical supplier, establishing business credit references, and getting my residential address approved to receive chemical shipments from them. Just so I could log onto their website and order 100g of TCPO. Which I did many months ago. It’s been back-ordered with their supplier since then. Who knows when or if I’ll ever actually get it.

800px-TCPO.png

This video from YouTuber NurdRage comes with a lot of caveats: the synthesis of TCPO from trichlorophenol and oxalyl chloride is relatively straightforward as syntheses go, and the starting materials are much easier to acquire than TCPO itself, but they’re still not at all grocery-store type compounds. And it’s not a thing to attempt without the expertise, equipment, and facilities to do it safely. Plus the creepy “Jigsaw” voice effect that the narrator uses to disguise his identity doesn’t exactly inspire confidence. There’s nothing illegal about this procedure, as far as I know, but I think he wants to remain anonymous so nobody can sue him if they try to play along at home and end up burning it down.

Nonetheless, I was grateful to find this video in the tubes, and will probably attempt it myself at some point. Famous last words, anyone?

Read more | Permalink | Comments |

Read more articles in Chemistry |

Digg this!

Share and Enjoy:
  • Digg
  • del.icio.us
  • Netvouz
  • DZone
  • ThisNext
  • MisterWong
  • Wists
  • Add to favorites
  • blogtercimlap
  • Facebook
  • Google Bookmarks
  • Gwar
  • LinkaGoGo
  • Live
  • MSN Reporter
  • MyShare
  • RSS
  • Slashdot
  • StumbleUpon
  • Suggest to Techmeme via Twitter
  • Technorati
  • Twitter

Atomic emission spectrum scarf

15-Feb-10

limorsilicon.jpg

Silicon_emission_spectrum.jpg

Our very own inimitable Becky Stern makes and sells these beautiful custom scarves featuring the atomic emission spectrum of your favorite element. Shown above is the “silicon” version (as modeled by AdaFruit’s likewise inimitable Limor Fried) but you can choose whichever element/spectrum you like. And here’s a handy-dandy Java applet from The University of Oregon that makes it easy to browse for your selection. Minimalists may prefer hydrogen or helium, but for my money it’s hard to pass up the rainbow-y goodness of, say, iron or tantalum. Want!

Read more | Permalink | Comments |

Read more articles in Chemistry |

Digg this!

Share and Enjoy:
  • Digg
  • del.icio.us
  • Netvouz
  • DZone
  • ThisNext
  • MisterWong
  • Wists
  • Add to favorites
  • blogtercimlap
  • Facebook
  • Google Bookmarks
  • Gwar
  • LinkaGoGo
  • Live
  • MSN Reporter
  • MyShare
  • RSS
  • Slashdot
  • StumbleUpon
  • Suggest to Techmeme via Twitter
  • Technorati
  • Twitter

Glenn Seaborg’s old mailing address

08-Feb-10

485px-Glenn_Seaborg_1964.png

The occasion of Dmitri Mendeleev’s birthday seemed like a good opportunity to recognize another great hero of the periodic table and to relate one of my favorite anecdotes about him: Glenn T. Seaborg (Wikipedia), who, among his various stellar achievements, won the 1951 Nobel Prize for “discoveries in the chemistry of the transuranium elements.” By the time of his death in 1999, Seaborg had participated in the discovery and isolation of ten superheavy elements. Shortly after the official 1997 recognition of the name seaborgium for element 106, Jeffrey Winters, writing in the January 1998 issue of Discover Magazine, made the following observation:

Not only is Seaborg the first living scientist to have an element named after him, he’s also the only person who could receive mail addressed only in elements: Seaborgium, Lawrencium (for the Lawrence Berkeley Laboratory where he still works), Berkelium, Californium, Americium. But don’t forget the zip code.

Naming an element after a living scientist generated significant controversy among the international chemistry community of the time. At a talk in 1995, Seaborg himself famously quipped: “There has been some reluctance on the part of the Commission for Nomenclature of Inorganic Chemistry of the International Union of Pure and Applied Chemistry to accept the name because I’m still alive and they can prove it, they say.”

Read more | Permalink | Comments |

Read more articles in Chemistry |

Digg this!

Share and Enjoy:
  • Digg
  • del.icio.us
  • Netvouz
  • DZone
  • ThisNext
  • MisterWong
  • Wists
  • Add to favorites
  • blogtercimlap
  • Facebook
  • Google Bookmarks
  • Gwar
  • LinkaGoGo
  • Live
  • MSN Reporter
  • MyShare
  • RSS
  • Slashdot
  • StumbleUpon
  • Suggest to Techmeme via Twitter
  • Technorati
  • Twitter

Maker Birthdays: Dmitri Mendeleev

08-Feb-10

DIMendeleevCab.jpg

Born on this date in 1834 in the small village of Aremzyani, in what was then considered Siberia, Dmitri Ivanovich Mendeleev (Wikipedia) would go on, in 1869, to publish the first periodic table of the chemical elements. Mendeleev used the periodicity he’d observed in the properties of then-known elements to accurately predict many of the properties of germanium, gallium, and scandium, which had not yet been discovered. Mendeleev died in St. Petersburg in 1907, at the age of 72. Element number 101 is named mendelevium in his honor.

Read more | Permalink | Comments |

Read more articles in Chemistry |

Digg this!

Share and Enjoy:
  • Digg
  • del.icio.us
  • Netvouz
  • DZone
  • ThisNext
  • MisterWong
  • Wists
  • Add to favorites
  • blogtercimlap
  • Facebook
  • Google Bookmarks
  • Gwar
  • LinkaGoGo
  • Live
  • MSN Reporter
  • MyShare
  • RSS
  • Slashdot
  • StumbleUpon
  • Suggest to Techmeme via Twitter
  • Technorati
  • Twitter

Flashback: The Florence Siphon Arabica Brewing & Extraction Apparatus

03-Feb-10

M17_Siphon_figureA.jpg

I thought I was really into coffee until I met John Edgar Park, host of Make: television, contributing writer to Make: Online, and author of several MAKE magazine articles. John takes his coffee seriously. Seriously. Case in point was when he devised and wrote a how-to for his Florence Siphon Brewing and Extraction Apparatus for MAKE Volume 17, our Lost Knowledge issue. This apparatus is sure to raise eyebrows (and spirits) next time you invite someone to your workshop for a cup of blessed joe. Check out the whole project in this week’s Flashback, and pick up a back issue of MAKE 17 over in the Maker Shed.

Make your own mad-scientist coffee machine.
By J. Edgar Park II

Aboard the dirigible Aeroship Phaedrus, two men are seated at a table in the onboard Laboratory:

“Doctor Liepold, would you kindly prescribe something to lift my depressed spirits?”
“Why of course, Captain Heffernan. What is it that ails you?”
“My mind feels sluggish and there is still much work to be done before daylight. I am drawing up charts for the expedition.”
“Ah, yes, I have just the thing. Sit a moment while I extract the invigorants from these wondrous beans.”
“Very good, thank you. What is that strange device, Herr Doktor?”
“I call it the Florence Siphon. It is an arabica brewing and extraction apparatus. Allow me to demonstrate. First, I fill this boiling flask with a quantity of pure spring water. It is a vessel of my own devising that can withstand great heat and pressure. I heat the flask, which causes the water to vaporize, passing through this tube here, through a filter, and into the beaker to my left. Here, the water commingles with precisely roasted and ground fruit of Coffea arabica. I give the slurry a rapid stirring to fully saturate the grounds, then wait.
“As my boiling flask cools, a vacuum is created, causing the very atmosphere of the Earth to push the liquid through the filter, leaving the grounds and all unsavory particulate matter behind. Thus the liquid, now filled with essences, oils, solubles, flavors, and vital invigorants, is returned to the flask. Allow me to unstopper it and pour you a dose.”
“Doctor! You have outdone yourself! I feel revitalized by this most miraculous potion.”

The vacuum siphon coffee brewing method dates back to the 1840s. It produces some of the cleanest, smoothest-tasting coffee of any method. Commercial vacuum pots are available, but I wanted to heighten the drama of vacuum brewing by taking it into the realm of the mad scientist’s lab. Thus the Florence Siphon was born!

After studying original patent drawings and existing devices, I identified these key features:
• Water is heated in a boiling flask that has a tube leading to a second vessel containing ground coffee.
• The tube must have a filter, to allow the water to flow through but not the grounds.
• The filter must be submerged during brewing, so as to maintain a seal with the boiling flask.
• The second vessel must be accessible for stirring the slurry.
• The boiling flask must be large enough to create a sufficient vacuum as it cools to “pull” the coffee back through.

One drawback to early vacuum brewers was the constant danger of exploding glass. Today, we have plenty of high-quality borosilicate glassware that’s up to the task — it just happens to be found in the lab, not the kitchen.

Filtration was another challenge. I tinkered with a few options (including an unfortunate foray into shower heads) before arriving at an inverted thistle tube. This is a type of bulbed funnel that’s easy to cover with filter cloth. (Thanks to Dr. Jim Callan from Avogadro’s Lab Supply for this suggestion.)

I assembled my funnel, stopper, tubing, filter, and a beaker for the grounds. I filled my flask with preheated water (small burners can take a while to boil 500ml), poured 38g of medium-ground coffee into the beaker, donned my goggles, and lit the burner.

The water began to bubble quickly, and soon went straight up the glass tube and over to the grounds. After about a minute, the flask was nearly empty and I extinguished the flame. At this point, there was an abundance of expanded water vapor (steam) inside the flask, which prevented the water from returning.

I stirred up the slurry with a stick and then waited with great excitement. Would the siphon be able to draw the coffee back up? At just about the 2-minute mark, I saw the gorgeous brown liquid begin its ascent. This is due to the vacuum created by the cooling and contraction of water vapor in the boiling flask. It was tentative at first, but as the boiling flask continued to cool, the coffee started to move quickly up the tube, over and then back down to the flask below. Within another 20 seconds, the journey was complete: 420ml of coffee made it back, leaving 80ml of water behind with the grounds.

I removed the stopper and poured myself a cup. It was perfect! Smooth, bright, clear, and clean. Vacuum coffee is a step above a French press, and leagues above drip. Plus, when you brew with the Florence Siphon you get to don your lab coat and cackle maniacally. What more could you want from a cup of coffee?

Here’s how to build your own Florence Siphon.

Read more | Permalink | Comments |

Read more articles in Chemistry |

Digg this!

Share and Enjoy:
  • Digg
  • del.icio.us
  • Netvouz
  • DZone
  • ThisNext
  • MisterWong
  • Wists
  • Add to favorites
  • blogtercimlap
  • Facebook
  • Google Bookmarks
  • Gwar
  • LinkaGoGo
  • Live
  • MSN Reporter
  • MyShare
  • RSS
  • Slashdot
  • StumbleUpon
  • Suggest to Techmeme via Twitter
  • Technorati
  • Twitter